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Visible-light-mediated catalyst-free synthesis of unnatural α-amino acids and peptide macrocycles

Chemistry

Visible-light-mediated catalyst-free synthesis of unnatural α-amino acids and peptide macrocycles

M. Wang, C. Wang, et al.

Discover a groundbreaking catalyst-free approach for synthesizing unnatural α-amino acids and peptide macrocycles using visible light! This innovative method leverages the unique properties of Katritzky salts, unlocking new pathways for deaminative hydroalkylation and cyclization, as revealed by the research conducted by Mengran Wang, Chao Wang, Yumei Huo, Xiaobo Dang, Hongxiang Xue, Liangyu Liu, Hongli Chai, Xiuling Xie, Zhixuan Li, Doudou Lu, and Zhaoqing Xu.

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