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Nickel catalyzed multicomponent stereodivergent synthesis of olefins enabled by electrochemistry, photocatalysis and photo-electrochemistry

Chemistry

Nickel catalyzed multicomponent stereodivergent synthesis of olefins enabled by electrochemistry, photocatalysis and photo-electrochemistry

C. Zhu, H. Yue, et al.

Discover a groundbreaking three-component, reductive cascade reaction for arylalkylation of alkynes, developed by Chen Zhu, Huifeng Yue, and Magnus Rueping. This innovative approach yields a variety of trisubstituted alkenes with unparalleled chemo- and stereoselectivity, showcasing exclusive formation of *E* and *Z* isomers through distinct electrochemical and photocatalytic methods.

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