logo
ResearchBunny Logo
Hierarchical single-crystal-to-single-crystal transformations of a monomer to a 1D-polymer and then to a 2D-polymer

Chemistry

Hierarchical single-crystal-to-single-crystal transformations of a monomer to a 1D-polymer and then to a 2D-polymer

H. Balan and K. M. Sureshan

This groundbreaking research by Haripriya Balan and Kana M. Sureshan reveals an innovative method for synthesizing a stable two-dimensional polymer through single-crystal-to-single-crystal transformations, opening new pathways in polymer chemistry. The study showcases the potential of thermally induced topochemical reactions for creating advanced materials.

00:00
00:00
Playback language: English
Abstract
This paper reports the single-crystal-to-single-crystal (SCSC) synthesis of a two-dimensional polymer (2D-P) via a thermally induced topochemical azide-alkyne cycloaddition (TAAC) reaction. A designed monomer with two azide and two alkyne units undergoes sequential SCSC polymerizations: first to a 1D polymer (1D-P) with 1,5-triazolyl linkages, and then to a 2D-P with both 1,5- and 1,4-triazolyl linkages in orthogonal directions. The 2D-P is thermally stable and can be exfoliated into 2D sheets.
Publisher
Nature Communications
Published On
Aug 05, 2024
Authors
Haripriya Balan, Kana M. Sureshan
Tags
single-crystal-to-single-crystal
two-dimensional polymer
thermally induced reactions
azide-alkyne cycloaddition
polymerization
1D and 2D structures
exfoliation

Related Publications

Explore these studies to deepen your understanding of the subject.

Efficacy of early PET-CT directed switch to carboplatin and paclitaxel based definitive chemoradiotherapy in patients with oesophageal cancer who have a poor early response to induction cisplatin and capecitabine in the UK: a multi-centre randomised controlled phase II trial
Medicine and Health

Efficacy of early PET-CT directed switch to carboplatin and paclitaxel based definitive chemoradiotherapy in patients with oesophageal cancer who have a poor early response to induction cisplatin and capecitabine in the UK: a multi-centre randomised controlled phase II trial

S. Mukherjee, C. N. Hurt, et al.

Risk factors for and pregnancy outcomes after SARS-CoV-2 in pregnancy according to disease severity: A nationwide cohort study with validation of the SARS-CoV-2 diagnosis of Nordic Federation of Societies of Obstetrics and Gynecology (NFOG)
Medicine and Health

Risk factors for and pregnancy outcomes after SARS-CoV-2 in pregnancy according to disease severity: A nationwide cohort study with validation of the SARS-CoV-2 diagnosis of Nordic Federation of Societies of Obstetrics and Gynecology (NFOG)

A. J. M. Aabakke, T. G. Petersen, et al.

Global, regional, and national burden of diabetes from 1990 to 2021, with projections of prevalence to 2050: a systematic analysis for the Global Burden of Disease Study 2021
Medicine and Health

Global, regional, and national burden of diabetes from 1990 to 2021, with projections of prevalence to 2050: a systematic analysis for the Global Burden of Disease Study 2021

G. 2. D. Collaborators, D. Kanyin, et al.

Phytochemical Composition and Health Benefits of Figs (Fresh and Dried): A Review of Literature from 2000 to 2022
Medicine and Health

Phytochemical Composition and Health Benefits of Figs (Fresh and Dried): A Review of Literature from 2000 to 2022

A. K. Sandhu, M. Islam, et al.

Listen, Learn & Level Up
Over 10,000 hours of research content in 25+ fields, available in 12+ languages.
No more digging through PDFs, just hit play and absorb the world's latest research in your language, on your time.
listen to research audio papers with researchbunny