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Efficient and versatile formation of glycosidic bonds via catalytic strain-release glycosylation with glycosyl *ortho*-2,2-dimethoxycarbonylcyclopropylbenzoate donors

Chemistry

Efficient and versatile formation of glycosidic bonds via catalytic strain-release glycosylation with glycosyl *ortho*-2,2-dimethoxycarbonylcyclopropylbenzoate donors

H. Ding, J. Lyu, et al.

This groundbreaking research by Han Ding, Jian Lyu, Xiao-Lin Zhang, Xiong Xiao, and Xue-Wei Liu unveils a novel catalytic glycosylation method using glycosyl *ortho*-2,2-dimethoxycarbonylcyclopropylbenzoates, facilitated by a scandium(III) catalyst. The study highlights an innovative activation mode that efficiently constructs diverse glycosidic bonds, paving the way for advanced oligosaccharide synthesis.

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