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Ag₃PO₄ enables the generation of long-lived radical cations for visible light-driven [2+2] and [4+2] pericyclic reactions

Chemistry

Ag₃PO₄ enables the generation of long-lived radical cations for visible light-driven [2+2] and [4+2] pericyclic reactions

L. Guo, R. Chu, et al.

Discover how Ag₃PO₄ acts as a remarkable catalyst for both intramolecular and intermolecular [2+2] and Diels-Alder cycloadditions, utilizing visible-light irradiation. This groundbreaking research by Lirong Guo and colleagues presents an innovative, additive-free method that generates long-lived radical cations, showcasing the potential of inorganic semiconductors for radical cation-mediated synthesis powered by sunlight.

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