ChemistryCommunications Chemistry
Switchable synthesis of natural-product-like lawsones and indenopyrazoles through regioselective ring-expansion of indantrione
B. Hu, W. Yan, et al.
Discover a groundbreaking method for synthesizing lawsones and indenopyrazoles through a metal-free, ring-expansion reaction using indantrione and diazomethanes. This innovative approach, conducted by Bingwei Hu, Wenxin Yan, Peiyun Jiang, Ling Jiang, Xu Yuan, Jun Lin, Yinchun Jiao, and Yi Jin, showcases excellent yields and diastereoselectivity, revealing significant potential for synthetic applications.
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