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This cutting-edge study explores the fascinating reactivity of N-methyl-4-sulfanylbenzamide (NMSB) at gold and silver nanoparticle aggregates under plasmonic excitation. By employing surface-enhanced Raman scattering (SERS), the authors reveal a hot electron-mediated transformation of NMSB into p-mercaptobenzamide and p-mercaptobenzonitrile, showcasing an unexpected non-thermal reaction pathway. Discover the exciting findings from this collaborative research by Anushree Dutta, Milan Ončák, Farhad Izadi, Eugene Arthur-Baidoo, João Ameixa, Stephan Denifl, and Ilko Bald.
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