Healable, Memorizable, and Transformable Lattice Structures Made of Stiff Polymers

Emerging transformable lattice structures provide promising paradigms to reversibly switch lattice configurations, thereby enabling their properties to be tuned on demand. The existing transformation mechanisms are limited to nonfracture deformation, such as origami, instability, shape memory, and liquid crystallinity. In this study, we present a class of transformable lattice structures enabled by fracture and shape-memory-assisted healing. The lattice structures are additively manufactured with a molecularly designed photopolymer capable of both fracture healing and shape memory. We show that 3D-architected lattice structures with various volume fractions can heal fractures and fully restore stiffness and strength over two to ten healing cycles. In addition, coupled with the shape-memory effect, the lattice structures can recover fracture-associated distortion and then heal fracture interfaces, thereby enabling healing of lattice wing damages, mode-l fractures, dent-induced crashes, and foreign-object impacts. Moreover, by harnessing the coupling of fracture and shape-memory-assisted healing, we demonstrate reversible configuration transformations of lattice structures to enable switching among property states of different stiffnesses, vibration transmittances, and acoustic absorptions. These healable, memorizable, and transformable lattice structures may find broad applications in next-generation aircraft panels, automobile frames, body armor, impact mitigators, vibration dampers, and acoustic modulators.