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Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

Chemistry

Easy access to medium-sized lactones through metal carbene migratory insertion enabled 1,4-palladium shift

Y. Yu, P. Chakraborty, et al.

This research, conducted by Yinghua Yu, Pushkin Chakraborty, Jinshuai Song, Lei Zhu, Chunsen Li, and Xueliang Huang, unveils an innovative method for synthesizing medium-sized lactones through site-selective C–H bond functionalization. It highlights a new, efficient pathway for producing biologically relevant compounds, overcoming significant challenges in ring closure, and sets the stage for late-stage modifications of complex molecules.

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~3 min • Beginner • English
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