Volatile compounds in olive oil significantly affect its quality and consumer preference. The oiling-out assisted liquid-liquid extraction (OA-LLE) method, combined with solvent-assisted flavor evaporation (SAFE), is proposed to improve the extraction of aroma compounds from extra virgin olive oil (EVOO). This combined approach (OA-LLE + SAFE) effectively overcomes the matrix effect of the oil and removes non-volatile compounds, leading to a deeper understanding of the EVOO aroma profile.