This paper explores the use of biological membranes with a nanopore sensor for detecting polysulfides in sulfur-based batteries. By studying the interaction between polysulfides and cyclodextrins, using NMR, molecular docking, and nanopore sensing, the researchers demonstrate single-molecule discrimination of polysulfide/cyclodextrin complexes differing by a single sulfur atom. This offers a new approach for electrolyte sensing and designing membranes with selective speciation of molecules to enhance battery lifetime.
Publisher
Communications Materials
Published On
Aug 13, 2020
Authors
Fanny Bétermier, Benjamin Cressiot, Giovanni Di Muccio, Nathalie Jarroux, Laurent Bacri, Blasco Morozzo della Rocca, Mauro Chinappi, Juan Pelta, Jean-Marie Tarascon
Tags
polysulfides
nanopore sensor
sulfur-based batteries
cyclodextrins
electrolyte sensing
membranes
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