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Rational molecular and device design enables organic solar cells approaching 20% efficiency

Engineering and Technology

Rational molecular and device design enables organic solar cells approaching 20% efficiency

J. Fu, Q. Yang, et al.

Discover how the innovative design of the non-fullerene acceptor o-BTP-eC9 leads to a significant power conversion efficiency of 19.9%, as presented by a team of researchers including Jiehao Fu, Qianguang Yang, and many more. This advancement not only reduces energy loss but also enhances operational stability in organic solar cells.

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Playback language: English
Abstract
To enhance the competitiveness of organic solar cells (OSCs), the light-absorbing molecules must meet several key criteria, including a weak-absorption charge transfer state, high dielectric constant, suitable surface energy, and proper crystallinity. This study presents a rational design of the non-fullerene acceptor o-BTP-eC9, guided by theoretical calculations, exhibiting distinct photoelectric properties compared to BTP-eC9. The o-BTP-eC9-based device demonstrates reduced energy loss and achieves a power conversion efficiency (PCE) of 18.7%. Furthermore, incorporating o-BTP-eC9 into a ternary system (PM6:BTP-C9:o-BTP-eC9) yields a PCE of 19.9% (19.5% certified), along with improved operational stability.
Publisher
Nature Communications
Published On
Feb 28, 2024
Authors
Jiehao Fu, Qianguang Yang, Peihao Huang, Sein Chung, Kilwon Cho, Zhipeng Kan, Heng Liu, Xinhui Lu, Yongwen Lang, Hanjian Lai, Feng He, Patrick W. K. Fong, Shirong Lu, Yang Yang, Zeyun Xiao, Gang Li
Tags
organic solar cells
non-fullerene acceptor
o-BTP-eC9
photoelectric properties
power conversion efficiency
energy loss
operational stability
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