This paper presents a novel mechanism for achieving high-speed and programmable actuation in disulfide crosslinked, thermally responsive hydrogels. By utilizing dynamic photo-activated disulfide bond exchange, spatio-selective network anisotropy is introduced, leading to actuation dominated by thermally driven conformational change rather than mass diffusion. Incorporation of photothermal fillers allows light-powered oscillation at frequencies up to 1.7 Hz. This, combined with programming versatility, enables the creation of robots with diverse high-speed motions such as swimming, walking, and rotating.
Publisher
Nature Communications
Published On
Nov 23, 2023
Authors
Chujun Ni, Di Chen, Xin Wen, Binjie Jin, Yi He, Tao Xie, Qian Zhao
Tags
hydrogels
actuation
photo-activated
disulfide bonds
robotics
thermally responsive
dynamic mechanisms
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