Economically viable co-production of methanol and sulfuric acid via direct methane oxidation

The direct oxidation of methane to methanol has been spotlighted research for decades, but has never been commercialized. This study introduces a cost-effective process for co-producing methanol and sulfuric acid through a direct oxidation of methane. In the initial phase, methane oxidation forms methyl bisulfate (CH3OSO3H), then transformed into methyl trifluoroacetate (CF3CO2CH3) via esterification, and hydrolyzed into methanol. This approach eliminates the need for energy-intensive separation of methyl bisulfate from sulfuric acid by replacing the former with methyl trifluoroacetate. Through superstructure optimization, our sequential process reduces the levelized cost of methanol to nearly two-fold reduction from the current market price. Importantly, this process demonstrates adaptability to smaller gas fields, assuring its economical operation across a broad range of gas fields. The broader application of this process could substantially mitigate global warming by utilizing methane, leading to a significantly more sustainable and economically beneficial methanol industry.

Jaehyung Im, Seok-Hyeon Cheong, Huyen Tran Dang, Nak-Kyoon Kim, Sungwon Hwang, Ki Bong Lee, Kyeongsu Kim, Hyunjoo Lee, Ung Lee