Chemistry

Branching mechanism of photoswitching in an Fe(II) polypyridyl complex explained by full singlet-triplet-quintet dynamics

T. Rozgonyi, G. Vankó, et al.

Discover how irradiation with visible light triggers the transformation of Fe(II) polypyridines from low-spin to high-spin states. This groundbreaking study, conducted by Tamás Rozgonyi, György Vankó, and Mátyás Pápai, delves into the dynamic photophysical processes of the [Fe(terpy)₂]²⁺ complex, unveiling sub-picosecond dynamics and intriguing breathing oscillations.

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