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Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping
ChemistryNature Communications

Bifunctional iron-catalyzed alkyne Z-selective hydroalkylation and tandem Z-E inversion via radical molding and flipping

Y. Zhang, D. Fu, et al.

Discover a groundbreaking bifunctional iron-catalyzed system that achieves Z-selective hydroalkylation with 100% atom utilization. This innovative approach not only supports a wide range of substrates but also introduces a photoinduced strategy for tailored alkene construction, as researched by Yongqiang Zhang, Dongmin Fu, Ziyang Chen, Rongqi Cui, Wenlong He, Hongyao Wang, Jiajin Chen, Yufei Chen, Shi-Jun Li, Yu Lan, Chunying Duan, and Yunhe Jin.... show more
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