Chemistry

A dual growth mode unique for organic crystals relies on mesoscopic liquid precursors

M. Yerragunta, A. Tiwari, et al.

Explore the fascinating world of crystal growth in organic solvents with insights from groundbreaking research by Manasa Yerragunta, Akash Tiwari, Rajshree Chakrabarti, Jeffrey D. Rimer, Bart Kahr, and Peter G. Vekilov. This study uncovers a unique dual growth mode in etioporphyrin I crystals, shedding light on the role of mesoscopic liquid precursors and their impact on crystal growth mechanisms.

00:00

Playback language: English

Index

Abstract

Organic solvents are widely used in synthesizing high-value crystals for various applications. However, the impact of replacing dominant hydrogen bonds and polar attractions in aqueous environments with weaker van der Waals forces on crystal growth mechanisms remains unclear. This study reveals a unique dual growth mode in etioporphyrin I crystals, enabled by mesoscopic liquid precursors. These precursors associate with crystal surfaces, forming layered stacks that grow laterally through direct solute incorporation from the solution, bypassing surface diffusion. The findings suggest this direct incorporation pathway and the nonclassical growth mode facilitated by liquid precursors are characteristic of organic solvents.

Publisher

Communications Chemistry

Published On

Aug 28, 2024

Authors

Manasa Yerragunta, Akash Tiwari, Rajshree Chakrabarti, Jeffrey D. Rimer, Bart Kahr, Peter G. Vekilov

Related Publications

Explore these studies to deepen your understanding of the subject.

Chemistry

A generative artificial intelligence framework based on a molecular diffusion model for the design of metal-organic frameworks for carbon capture

H. Park, X. Yan, et al.

Engineering and Technology

A double-layered liquid metal-based electrochemical sensing system on fabric as a wearable detector for glucose in sweat

X. Chen, H. Wan, et al.

Environmental Studies and Forestry

A new scheme for low-carbon recycling of urban and rural organic waste based on carbon footprint assessment: A case study in China

K. Zhou, Y. Li, et al.

Engineering and Technology

A dual-mode fiber-shaped flexible capacitive strain sensor fabricated by direct ink writing technology for wearable and implantable health monitoring applications

C. Zhang, W. Ouyang, et al.

Listen, Learn & Level Up

Over 10,000 hours of research content in 25+ fields, available in 12+ languages.

No more digging through PDFs, just hit play and absorb the world's latest research in your language, on your time.

listen to research audio papers with researchbunny