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Observation of site-selective chemical bond changes via ultrafast chemical shifts

Chemistry

Observation of site-selective chemical bond changes via ultrafast chemical shifts

A. Al-haddad, S. Oberli, et al.

This groundbreaking research showcases the capability to initiate and observe ultrafast electron rearrangement in carbon monoxide molecules, specifically at the oxygen atom. By examining the chemical shifts of carbon core-electron binding energy, this study unveils sensitivity to chemical environment changes and transient electronic dynamics, paving the way for insights into energy and charge transport processes in complex systems. Conducted by an expert team of authors, this work is poised to revolutionize our understanding of chemical reaction processes.

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Playback language: English
Abstract
This paper demonstrates the ability to initiate and track ultrafast electron rearrangement and chemical bond breaking site-specifically in real time for the carbon monoxide diatomic molecule using a local resonant x-ray pump at the oxygen atom and probing the chemical shifts of the carbon core-electron binding energy. The technique shows sensitivity to chemical environment changes including transient electronic excited state dynamics, providing a route to investigate energy and charge transport processes in more complex systems.
Publisher
Nature Communications
Published On
Nov 22, 2022
Authors
Andre Al-Haddad, Solène Oberli, Jesús González-Vázquez, Maximilian Bucher, Gilles Doumy, Phay Ho, Jacek Krzywinski, Thomas J. Lane, Alberto Lutman, Agostino Marinelli, Timothy J. Maxwell, Stefan Moeller, Stephen T. Pratt, Dipanwita Ray, Ron Shepard, Stephen H. Southworth, Álvaro Vázquez-Mayagoitia, Peter Walter, Linda Young, Antonio Picón, Christoph Bostedt
Tags
ultrafast electron rearrangement
chemical bond breaking
carbon monoxide
x-ray pump
chemical shifts
excited state dynamics
energy transport
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