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Coagulation of trace arsenic and cadmium from drinking water using titanium potassium oxalate

Environmental Studies and Forestry

Coagulation of trace arsenic and cadmium from drinking water using titanium potassium oxalate

J. Zhou, Y. Liu, et al.

Discover how titanium potassium oxalate revolutionizes drinking water safety by effectively removing arsenic and cadmium, outperforming traditional coagulants. This innovative solution, presented by Juanjuan Zhou, Yanwei Liu, Bingqian Li, Huashou Li, Guikui Chen, and Rongliang Qiu, not only enhances water quality but also reduces hardness, making it a cost-effective choice for environmental health.

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Playback language: English
Abstract
Coagulation using titanium potassium oxalate (K₂TiO(C₂O₄)₂) effectively removes arsenite, arsenate, and cadmium from drinking water, exceeding the performance of traditional coagulants like Fe₂(SO₄)₃ and Al₂(SO₄)₃. A 120 µmol/L K₂TiO(C₂O₄)₂ dose removes over 90% of As and Cd, even at initial concentrations ten times the maximum contaminant levels. The mechanism involves K₂TiO(C₂O₄)₂ reacting with calcium ions to form calcium oxalate, while titanium hydrolyzes to form hydrous titanium oxide. Arsenic is removed via complexation with hydrous titanium oxide, while cadmium removal involves adsorption and mixed-crystal formation with calcium oxalate. This offers a cost-effective solution for simultaneous heavy metal removal, improving drinking water safety and reducing water hardness.
Publisher
npj Clean Water
Published On
Feb 17, 2023
Authors
Juanjuan Zhou, Yanwei Liu, Bingqian Li, Huashou Li, Guikui Chen, Rongliang Qiu
Tags
titanium potassium oxalate
arsenic removal
cadmium removal
drinking water
heavy metals
coagulation
water safety
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